Preparation of Co and Ni dispersed porous carbon from metal naphthenate-phenolic and fran resin hybrid

Takahiro Takei, Satoshi Inoue, Qiang Dong, Yoshinori Yonesaki, Nobuhiro Kumada, Nobukazu Kinomura

Research output: Contribution to journalArticlepeer-review

Abstract

Metal-dispersed porous carbon was prepared from phenolic or furan resin mixed with Co or Ni naphthenate. The formed metal particles in these metal-dispersed porous carbons are apparently smaller than those in the metal-carbon composite prepared from metal nitrate. In the case of the metal-dispersed porous carbon prepared from phenolic resin and Co naphthenate, graphite phase was formed above 800°C around Co nanoparticles. XRD patterns and TEM micrographs confirm that metal naphthenate works as a metal source from which dispersed nanosize metal particles formed. The porous carbons prepared from phenolic or furan resin with Co or Ni naphthenate have specific surface area of approx. 400m2/g. For the porous carbon from phenolic resin, mesopore was formed within the sample by cracking or breaking up the large particles. These results indicate that mixing of phenol monomer and the naphthenate before polymerization results in development of mesopore.

Original languageEnglish
Pages (from-to)470-476
Number of pages7
JournalJournal of the Ceramic Society of Japan
Volume119
Issue number1390
DOIs
Publication statusPublished - 2011 Jun

Keywords

  • Activated carbon
  • Carbonization
  • Graphite
  • Hybrid
  • Metal naphthenate
  • Porous property

ASJC Scopus subject areas

  • Ceramics and Composites
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry

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