Preparation, Electronic and Liquid Crystalline Properties of Electron-Accepting Azaacene Derivatives

Takashi Takeda, Tomohiro Ikemoto, Shunsuke Yamamoto, Wakana Matsuda, Shu Seki, Masaya Mitsuishi, Tomoyuki Akutagawa

    Research output: Contribution to journalArticlepeer-review

    Abstract

    A series of electron-accepting azaacene-type materials 1-4 with different kinds and degrees of intermolecular interactions were synthesized. Simple modification of the terminal substituents significantly modulated the photophysical and electrochemical properties. The degree of weak intermolecular interaction determined the emergence of a liquid crystalline (LC) phase for each compound. Dipole-dipole interaction, π- π interaction, and van der Waals interaction all contributed to stabilize the LC phase of 1 and 2. The introduction of strong hydrogen bonding interaction enabled the formation of a highly ordered LC phase in 4. Charge-transport properties of 1, 2, and 4 were also investigated.

    Original languageEnglish
    Pages (from-to)13694-13703
    Number of pages10
    JournalACS Omega
    Volume3
    Issue number10
    DOIs
    Publication statusPublished - 2018 Oct 19

    ASJC Scopus subject areas

    • Chemistry(all)
    • Chemical Engineering(all)

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