Preparation, characterization, and catalytic behavior of Rh-Mn double oxide on SiO2

K. Kunimori, T. Wakasugi, Z. Hu, H. Oyanagi, M. Imai, H. Asano, T. Uchijima

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Rh double-oxide compound (MnRh2O4) was formed by air calcination treatment of manganese oxide-promoted Rh/SiO2 catalyst at 900 °C, and characterized by Rietveld analysis of the X-ray diffraction pattern. The MnRh2O4 particles on SiO2 were reduced to smaller Rh metal particles by H2 treatment at 300 °C, and this catalyst system exhibited a strong Rh-MnOx interaction behavior in catalytic studies of ethane hydrogenolysis and cyclohexane dehydrogenation reactions.

Original languageEnglish
Pages (from-to)337-343
Number of pages7
JournalCatalysis Letters
Volume7
Issue number5-6
DOIs
Publication statusPublished - 1990 Sep
Externally publishedYes

Keywords

  • Metal-oxide interaction
  • Rh double oxide
  • Rietveld analysis
  • cyclohexane dehydrogenation
  • ethane hydrogenolysis
  • rhodium manganese oxide compound

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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