Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative

Kozo Toyota, Yasuhisa Ishikawa, Kotaro Shirabe, Masaaki Yoshifuji, Kengo Okada, Ken Hirotsu

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

1,3‐Bis(2,4,6‐tri‐t‐butylphenyl)‐1,3‐diphosphaallene (1) reacted with elemental sulfur under wet reaction conditions to give cis‐ and trans‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐thiadiphosphetane 2,4‐disulfide (cis‐2 and trans‐2) and cis‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐oxadiphosphetane 2,4‐disulfide (cis‐3). The structure of cis‐3 was determined by X‐ray crystallography, and the cis/trans isomerization of 2 was studied.

Original languageEnglish
Pages (from-to)279-285
Number of pages7
JournalHeteroatom Chemistry
Volume4
Issue number2-3
DOIs
Publication statusPublished - 1993 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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