Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane stabilized by intramolecular coordination

Masaaki Yoshifuji; Kazunori Kamijo; Kozo Toyota

doi:10.1016/S0040-4039(00)76716-5

Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane stabilized by intramolecular coordination

Masaaki Yoshifuji, Kazunori Kamijo, Kozo Toyota

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

[2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a strong participation of the nitrogen lone pair in the stabilization of the dithioxophosphoryl group.

Original language	English
Pages (from-to)	3971-3974
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	23
DOIs	https://doi.org/10.1016/S0040-4039(00)76716-5
Publication status	Published - 1994 Jun 6
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)76716-5

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title = "Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane stabilized by intramolecular coordination",

abstract = "[2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a strong participation of the nitrogen lone pair in the stabilization of the dithioxophosphoryl group.",

author = "Masaaki Yoshifuji and Kazunori Kamijo and Kozo Toyota",

note = "Funding Information: Acknowledgment: This work was supportedi n part by the Grants-in-Aid for Scientific Researchf rom the Ministry of Education, Science and Culture, JapaneseG overnment (Nos. 03233105a nd 02403008)a nd the Research Fund from the Asahi Glass Foundation. The authors also thank Tosoh Akzo Co., Ltd., for donationo f organolithiumr eagents.",

year = "1994",

month = jun,

day = "6",

doi = "10.1016/S0040-4039(00)76716-5",

language = "English",

volume = "35",

pages = "3971--3974",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "23",

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TY - JOUR

T1 - Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane stabilized by intramolecular coordination

AU - Yoshifuji, Masaaki

AU - Kamijo, Kazunori

AU - Toyota, Kozo

N1 - Funding Information: Acknowledgment: This work was supportedi n part by the Grants-in-Aid for Scientific Researchf rom the Ministry of Education, Science and Culture, JapaneseG overnment (Nos. 03233105a nd 02403008)a nd the Research Fund from the Asahi Glass Foundation. The authors also thank Tosoh Akzo Co., Ltd., for donationo f organolithiumr eagents.

PY - 1994/6/6

Y1 - 1994/6/6

N2 - [2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a strong participation of the nitrogen lone pair in the stabilization of the dithioxophosphoryl group.

AB - [2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a strong participation of the nitrogen lone pair in the stabilization of the dithioxophosphoryl group.

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U2 - 10.1016/S0040-4039(00)76716-5

DO - 10.1016/S0040-4039(00)76716-5

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VL - 35

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EP - 3974

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 23

ER -

Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane stabilized by intramolecular coordination

Abstract

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