Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane stabilized by intramolecular coordination

Masaaki Yoshifuji, Kazunori Kamijo, Kozo Toyota

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

[2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a strong participation of the nitrogen lone pair in the stabilization of the dithioxophosphoryl group.

Original languageEnglish
Pages (from-to)3971-3974
Number of pages4
JournalTetrahedron Letters
Volume35
Issue number23
DOIs
Publication statusPublished - 1994 Jun 6

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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