Abstract
[2,4-Di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane was prepared by the reaction of the corresponding phosphine and elemental sulfur. The structure of the dithioxophosphorane was analyzed by X-ray crystallography, which indicated a strong participation of the nitrogen lone pair in the stabilization of the dithioxophosphoryl group.
| Original language | English |
|---|---|
| Pages (from-to) | 3971-3974 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 35 |
| Issue number | 23 |
| DOIs | |
| Publication status | Published - 1994 Jun 6 |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Yoshifuji, M., Kamijo, K., & Toyota, K. (1994). Preparation and x-ray structure of [2,4-di-t-butyl-6-(N,N-dimethylaminomethyl)phenyl]dithioxophosphorane stabilized by intramolecular coordination. Tetrahedron Letters, 35(23), 3971-3974. https://doi.org/10.1016/S0040-4039(00)76716-5