Preparation and properties of some stable captodative diphosphenes carrying the N‐(9‐fluorenyl)‐N‐mesitylamino group as an electron‐donating new sterically protecting auxiliary

Masatoshi Abe, Kozo Toyota, Masaaki Yoshifuji

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The N‐(9‐fluorenyl)‐N‐mesitylamino group was utilized as an electron‐donating new sterically protecting group and thus several captodative 1‐amino‐2‐aryldiphosphenes were prepared. The push‐pull substituent effect on the ‐PP‐ bond was demonstrated by 31P NMR, and the reactivities of the captodative diphosphenes were studied.

Original languageEnglish
Pages (from-to)427-432
Number of pages6
JournalHeteroatom Chemistry
Volume4
Issue number5
DOIs
Publication statusPublished - 1993 Oct

ASJC Scopus subject areas

  • Chemistry(all)

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