Preparation and properties of some stable captodative diphosphenes carrying the N‐(9‐fluorenyl)‐N‐mesitylamino group as an electron‐donating new sterically protecting auxiliary

Masatoshi Abe; Kozo Toyota; Masaaki Yoshifuji

doi:10.1002/hc.520040504

Preparation and properties of some stable captodative diphosphenes carrying the N‐(9‐fluorenyl)‐N‐mesitylamino group as an electron‐donating new sterically protecting auxiliary

Masatoshi Abe, Kozo Toyota, Masaaki Yoshifuji

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The N‐(9‐fluorenyl)‐N‐mesitylamino group was utilized as an electron‐donating new sterically protecting group and thus several captodative 1‐amino‐2‐aryldiphosphenes were prepared. The push‐pull substituent effect on the ‐PP‐ bond was demonstrated by ³¹P NMR, and the reactivities of the captodative diphosphenes were studied.

Original language	English
Pages (from-to)	427-432
Number of pages	6
Journal	Heteroatom Chemistry
Volume	4
Issue number	5
DOIs	https://doi.org/10.1002/hc.520040504
Publication status	Published - 1993 Oct

ASJC Scopus subject areas

Chemistry(all)

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abstract = "The N‐(9‐fluorenyl)‐N‐mesitylamino group was utilized as an electron‐donating new sterically protecting group and thus several captodative 1‐amino‐2‐aryldiphosphenes were prepared. The push‐pull substituent effect on the ‐PP‐ bond was demonstrated by 31P NMR, and the reactivities of the captodative diphosphenes were studied.",

author = "Masatoshi Abe and Kozo Toyota and Masaaki Yoshifuji",

year = "1993",

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AU - Toyota, Kozo

AU - Yoshifuji, Masaaki

PY - 1993/10

Y1 - 1993/10

N2 - The N‐(9‐fluorenyl)‐N‐mesitylamino group was utilized as an electron‐donating new sterically protecting group and thus several captodative 1‐amino‐2‐aryldiphosphenes were prepared. The push‐pull substituent effect on the ‐PP‐ bond was demonstrated by 31P NMR, and the reactivities of the captodative diphosphenes were studied.

AB - The N‐(9‐fluorenyl)‐N‐mesitylamino group was utilized as an electron‐donating new sterically protecting group and thus several captodative 1‐amino‐2‐aryldiphosphenes were prepared. The push‐pull substituent effect on the ‐PP‐ bond was demonstrated by 31P NMR, and the reactivities of the captodative diphosphenes were studied.

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ER -

Preparation and properties of some stable captodative diphosphenes carrying the N‐(9‐fluorenyl)‐N‐mesitylamino group as an electron‐donating new sterically protecting auxiliary

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