Preparation and properties of 2,2-Bissilyl-1,3-dithia-2-silacyclopent-4-enes and related compounds

Shinobu Tsutsui, Masae Takahashi, Kenkichi Sakamoto

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

Several 1,3-dithia-2-silacyclopent-4-ene (dithiasilole) derivatives were prepared by the reactions of cis-NaS-HC=CH-SNa with the corresponding dichlorosilanes. The compounds formed charge-transfer (CT) complexes with tetracyanoethylene in CH2Cl2. The UV-vis spectra of the CT complexes indicated that the ionization potential of 2,2-bis(trimethylsilyl)dithiasilole was smaller than that of 2,2-dimethyldithiasilole. The results were explained by the σ(Si-R)-π interactions resulting in a higher HOMO level. Ab initio MO calculations supported the experimental results.

Original languageEnglish
Pages (from-to)1376-1377
Number of pages2
JournalChemistry Letters
Issue number12
DOIs
Publication statusPublished - 2000 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint Dive into the research topics of 'Preparation and properties of 2,2-Bissilyl-1,3-dithia-2-silacyclopent-4-enes and related compounds'. Together they form a unique fingerprint.

Cite this