Preparation and characterization of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) Langmuir-Blodgett film

Mohammod Aminuzzaman; Yuko Kado; Masaya Mitsuishi; Tokuji Miyashita

doi:10.1295/polymj.35.785

Preparation and characterization of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) Langmuir-Blodgett film

Mohammod Aminuzzaman, Yuko Kado, Masaya Mitsuishi, Tokuji Miyashita

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

The monolayer behavior of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) (pC7F15MAA) spread on the air-water interface was investigated by measurement of surface pressure-area isotherm at different subphase temperatures. The monolayer of pC7F15MAA was transferred onto solid substrates as Y-type Langmuir-Blodgett (LB) film and the monolayer thickness was calculated by X-Ray diffraction techniques and surface plasmon measurements. Wettability and the surface structure of the LB film were investigated by measuring the static contact angle (cos θ) of water on the surface. The wettability varied slightly with increasing temperature. The critical surface tension measurement suggests that the surface of pC7F15MAA LB film covered mainly with CF₃ groups.

Original language	English
Pages (from-to)	785-790
Number of pages	6
Journal	Polymer Journal
Volume	35
Issue number	10
DOIs	https://doi.org/10.1295/polymj.35.785
Publication status	Published - 2003

Keywords

Fluorinated polymer
Langmuir-Blodgett film
Surface plasmon resonance

ASJC Scopus subject areas

Polymers and Plastics
Materials Chemistry

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10.1295/polymj.35.785

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title = "Preparation and characterization of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) Langmuir-Blodgett film",

abstract = "The monolayer behavior of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) (pC7F15MAA) spread on the air-water interface was investigated by measurement of surface pressure-area isotherm at different subphase temperatures. The monolayer of pC7F15MAA was transferred onto solid substrates as Y-type Langmuir-Blodgett (LB) film and the monolayer thickness was calculated by X-Ray diffraction techniques and surface plasmon measurements. Wettability and the surface structure of the LB film were investigated by measuring the static contact angle (cos θ) of water on the surface. The wettability varied slightly with increasing temperature. The critical surface tension measurement suggests that the surface of pC7F15MAA LB film covered mainly with CF3 groups.",

keywords = "Fluorinated polymer, Langmuir-Blodgett film, Surface plasmon resonance",

author = "Mohammod Aminuzzaman and Yuko Kado and Masaya Mitsuishi and Tokuji Miyashita",

note = "Funding Information: Acknowledgment. The authors would like to thank Prof. H. Nakanishi for the use of XRD instrument. This work was supported by a Grant-in-Aid for Scientific Research (No.14205130) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.",

year = "2003",

doi = "10.1295/polymj.35.785",

language = "English",

volume = "35",

pages = "785--790",

journal = "Polymer Journal",

issn = "0032-3896",

publisher = "Nature Publishing Group",

number = "10",

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TY - JOUR

T1 - Preparation and characterization of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) Langmuir-Blodgett film

AU - Aminuzzaman, Mohammod

AU - Kado, Yuko

AU - Mitsuishi, Masaya

AU - Miyashita, Tokuji

N1 - Funding Information: Acknowledgment. The authors would like to thank Prof. H. Nakanishi for the use of XRD instrument. This work was supported by a Grant-in-Aid for Scientific Research (No.14205130) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.

PY - 2003

Y1 - 2003

N2 - The monolayer behavior of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) (pC7F15MAA) spread on the air-water interface was investigated by measurement of surface pressure-area isotherm at different subphase temperatures. The monolayer of pC7F15MAA was transferred onto solid substrates as Y-type Langmuir-Blodgett (LB) film and the monolayer thickness was calculated by X-Ray diffraction techniques and surface plasmon measurements. Wettability and the surface structure of the LB film were investigated by measuring the static contact angle (cos θ) of water on the surface. The wettability varied slightly with increasing temperature. The critical surface tension measurement suggests that the surface of pC7F15MAA LB film covered mainly with CF3 groups.

AB - The monolayer behavior of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) (pC7F15MAA) spread on the air-water interface was investigated by measurement of surface pressure-area isotherm at different subphase temperatures. The monolayer of pC7F15MAA was transferred onto solid substrates as Y-type Langmuir-Blodgett (LB) film and the monolayer thickness was calculated by X-Ray diffraction techniques and surface plasmon measurements. Wettability and the surface structure of the LB film were investigated by measuring the static contact angle (cos θ) of water on the surface. The wettability varied slightly with increasing temperature. The critical surface tension measurement suggests that the surface of pC7F15MAA LB film covered mainly with CF3 groups.

KW - Fluorinated polymer

KW - Langmuir-Blodgett film

KW - Surface plasmon resonance

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DO - 10.1295/polymj.35.785

M3 - Article

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VL - 35

SP - 785

EP - 790

JO - Polymer Journal

JF - Polymer Journal

SN - 0032-3896

IS - 10

ER -

Preparation and characterization of poly(N-1H,1H-pentadecafluorooctylmethacrylamide) Langmuir-Blodgett film

Abstract

Keywords

ASJC Scopus subject areas

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