Preparation and characterization of citratoperoxotitanate barium compound for BaTiO3 synthesis

Masaru Tada, Kohji Tomita, Valery Petrykin, Masato Kakihana

Research output: Contribution to journalConference articlepeer-review

23 Citations (Scopus)

Abstract

An orange precipitate has been obtained from the solution containing ammonium citratoperoxotitanate - (NH4)8[Ti4(C6H4O7 )4(O2)4] and barium nitrate. The powder XRD pattern of this product corresponded to a new phase with the monoclinic unit cell a = 18.345(1) Å, b = 11.0862(9) Å, c = 13.1003(9) Å and β = 117.133(4)°. Based on the TG-DTA, Raman spectroscopy and XRD analysis of the calcination product, we have concluded that the obtained compound is Ba[Ti(C6H4O7)O2]·2H2 O (Ba4[Ti4(C6H4O7)4 (O2)4]·8H2O, taking into account the structure of the complex anion). This compound has been demonstrated to be a convenient precursor for synthesis of BaTiO3 by simple calcination in air at the reduced temperature of 630 °C.

Original languageEnglish
Pages (from-to)293-297
Number of pages5
JournalSolid State Ionics
Volume151
Issue number1-4
DOIs
Publication statusPublished - 2002 Nov 1
Externally publishedYes
EventSSP- 2000 - Tokyo, Japan
Duration: 2000 Dec 112000 Dec 13

Keywords

  • BaTiO
  • Barium
  • Citratoperoxotitanate

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Fingerprint Dive into the research topics of 'Preparation and characterization of citratoperoxotitanate barium compound for BaTiO<sub>3</sub> synthesis'. Together they form a unique fingerprint.

Cite this