Preparation and characterization of a π-conjugated donor-accepter-type ligand molecule with redox abilities

Keiichi Katoh; Naoki Sato

doi:10.1246/cl.2008.618

Preparation and characterization of a π-conjugated donor-accepter-type ligand molecule with redox abilities

Keiichi Katoh, Naoki Sato

Research output: Contribution to journal › Article › peer-review

Abstract

We have synthesized a zwitterion-like molecule 1 having an N,N,N-tridentate ligand site for metal complexation. Compound 1 exhibited negative solvatochromism of the intramolecular charge-transfer (ICT) band in its UV-visible absorption spectrum for different polarity of solvents. Its anion radical (1^-) was generated from both electrical and chemical reduction of the p-naphthoquinone moiety.

Original language	English
Pages (from-to)	618-619
Number of pages	2
Journal	Chemistry Letters
Volume	37
Issue number	6
DOIs	https://doi.org/10.1246/cl.2008.618
Publication status	Published - 2008 Jun 5
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.2008.618

Fingerprint Dive into the research topics of 'Preparation and characterization of a π-conjugated donor-accepter-type ligand molecule with redox abilities'. Together they form a unique fingerprint.

Cite this

@article{af803483521849148e89b73990269002,

title = "Preparation and characterization of a π-conjugated donor-accepter-type ligand molecule with redox abilities",

abstract = "We have synthesized a zwitterion-like molecule 1 having an N,N,N-tridentate ligand site for metal complexation. Compound 1 exhibited negative solvatochromism of the intramolecular charge-transfer (ICT) band in its UV-visible absorption spectrum for different polarity of solvents. Its anion radical (1-) was generated from both electrical and chemical reduction of the p-naphthoquinone moiety.",

author = "Keiichi Katoh and Naoki Sato",

year = "2008",

month = jun,

day = "5",

doi = "10.1246/cl.2008.618",

language = "English",

volume = "37",

pages = "618--619",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "6",

}

TY - JOUR

T1 - Preparation and characterization of a π-conjugated donor-accepter-type ligand molecule with redox abilities

AU - Katoh, Keiichi

AU - Sato, Naoki

PY - 2008/6/5

Y1 - 2008/6/5

N2 - We have synthesized a zwitterion-like molecule 1 having an N,N,N-tridentate ligand site for metal complexation. Compound 1 exhibited negative solvatochromism of the intramolecular charge-transfer (ICT) band in its UV-visible absorption spectrum for different polarity of solvents. Its anion radical (1-) was generated from both electrical and chemical reduction of the p-naphthoquinone moiety.

AB - We have synthesized a zwitterion-like molecule 1 having an N,N,N-tridentate ligand site for metal complexation. Compound 1 exhibited negative solvatochromism of the intramolecular charge-transfer (ICT) band in its UV-visible absorption spectrum for different polarity of solvents. Its anion radical (1-) was generated from both electrical and chemical reduction of the p-naphthoquinone moiety.

UR - http://www.scopus.com/inward/record.url?scp=48249149118&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=48249149118&partnerID=8YFLogxK

U2 - 10.1246/cl.2008.618

DO - 10.1246/cl.2008.618

M3 - Article

AN - SCOPUS:48249149118

VL - 37

SP - 618

EP - 619

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 6

ER -

Preparation and characterization of a π-conjugated donor-accepter-type ligand molecule with redox abilities

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this