Premelting behavior of a Langmuir-Blodgett film of dioctadecyldimethylammonium-Au(dmit)2 salt

Shin Ichi Morita, Akifumi Ikehata, Yasuhiro F. Miura, Michio Sugi, Yukihiro Ozaki

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

Premelting behavior of a Langmuir-Bodgett (LB) film of dioctadecyldimethylammonium-Au(dmit)2 salt was investigated using infrared transmission spectroscopy. It was observed that there were four ordered stages in the LB film below the order-disorder transition between 105-110 °C. It was also observed that the orientation and conformation of hydrocarbon chain did not change significantly in the temperature range of 30-50 °C. The results show that 2C18-Au(dmit)2 LB film exhibits high inplane conductivity of 2 Scm-1 after electrochemical oxidation.

Original languageEnglish
Pages (from-to)19354-19360
Number of pages7
JournalJournal of Physical Chemistry B
Volume108
Issue number50
DOIs
Publication statusPublished - 2004 Dec 16
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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