TY - JOUR
T1 - Preferential adsorption of solvents on the cathode surface of lithium ion batteries
AU - Yu, Le
AU - Liu, Huijin
AU - Wang, Yan
AU - Kuwata, Naoaki
AU - Osawa, Masatoshi
AU - Kawamura, Junichi
AU - Ye, Shen
PY - 2013/5/27
Y1 - 2013/5/27
N2 - The adsorption structures of solvents on the surface of LiCoO2, which is the most widely used cathode material for Li-ion batteries, in contact with nonaqueous electrolyte solutions of carbonate esters have been characterized by insitu sum frequency generation (SFG) spectroscopy. The cyclic carbonate of ethylene carbonate (EC) is preferentially adsorbed on the LiCoO2 surface, in contrast to linear carbonates, such as dimethyl carbonate (DMC).
AB - The adsorption structures of solvents on the surface of LiCoO2, which is the most widely used cathode material for Li-ion batteries, in contact with nonaqueous electrolyte solutions of carbonate esters have been characterized by insitu sum frequency generation (SFG) spectroscopy. The cyclic carbonate of ethylene carbonate (EC) is preferentially adsorbed on the LiCoO2 surface, in contrast to linear carbonates, such as dimethyl carbonate (DMC).
KW - electrode-solution interfaces
KW - lithium ion batteries
KW - nonlinear vibrational spectroscopy
KW - solvent adsorption
UR - http://www.scopus.com/inward/record.url?scp=84878084912&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84878084912&partnerID=8YFLogxK
U2 - 10.1002/anie.201209976
DO - 10.1002/anie.201209976
M3 - Article
C2 - 23616480
AN - SCOPUS:84878084912
SN - 1433-7851
VL - 52
SP - 5753
EP - 5756
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 22
ER -
