Abstract
Square-shaped blue single crystals of nickel-doped magnesium aluminum spinel have been pulled down from the melt, by the micro-pulling-down method. The absorption spectra of doped samples show three broad absorption bands. According to the absorption map and the chemical analysis of these crystals, the effective segregation coefficients of Ni2+ in MgAl2O4 at low doping concentration (CNi〈 2 mol%) were calculated to be less than the unity, due to the vaporization behavior of NiO. Strong infrared broad emission in the eye-safe region peaking at 1.3 μm have been systematically investigated under high-intensity pulsed Nd:YAG laser excitation in the red region. The suitable absorption for InGaAs laser-diode pumping combined with long decay time of the infrared emissions and the good thermal properties of MgAl2O4 make Ni2+-MgAl2O4 a promising laser crystal.
Original language | English |
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Pages (from-to) | 47-49 |
Number of pages | 3 |
Journal | Optical Materials |
Volume | 30 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2007 Sep |
Keywords
- 3d transition metal ion
- Absorption
- Infrared emission
- Micro-pulling-down method
- Nickel
- Spinel
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Atomic and Molecular Physics, and Optics
- Spectroscopy
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Electrical and Electronic Engineering