Porphyrin-based coordination polymer composed of layered pillarless two-dimensional networks

Rie Makiura; Ryo Usui; Ehmke Pohl; Kosmas Prassides

doi:10.1246/cl.140275

Porphyrin-based coordination polymer composed of layered pillarless two-dimensional networks

Rie Makiura, Ryo Usui, Ehmke Pohl, Kosmas Prassides

Advanced Institute for Materials Research (AIMR)

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H₂O)Zn₂(H₂O)₂] (ZnTCPP: 5,10,15,20- tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.

Original language	English
Pages (from-to)	1161-1163
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	7
DOIs	https://doi.org/10.1246/cl.140275
Publication status	Published - 2014

ASJC Scopus subject areas

Chemistry(all)

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abstract = "Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20- tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.",

author = "Rie Makiura and Ryo Usui and Ehmke Pohl and Kosmas Prassides",

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doi = "10.1246/cl.140275",

language = "English",

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journal = "Chemistry Letters",

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AU - Makiura, Rie

AU - Usui, Ryo

AU - Pohl, Ehmke

AU - Prassides, Kosmas

PY - 2014

Y1 - 2014

N2 - Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20- tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.

AB - Single crystals of a layer-structured coordination polymer, BNAS-11 [ZnTCPP(H2O)Zn2(H2O)2] (ZnTCPP: 5,10,15,20- tetrakis(4-carboxyphenyl)porphyrinatozinc(II)), were obtained. Tetratopic ZnTCPP molecules are connected through dimer zinc paddle-wheel secondary building units and form a two-dimensional (2D) network with square grids. The layers are stacked electrostatically without the need of binding pillar ligands.

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Porphyrin-based coordination polymer composed of layered pillarless two-dimensional networks

Abstract

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