Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide

Yoshinao Nakagawa; Keigo Kamata; Miyuki Kotani; Kazuya Yamaguchi; Noritaka Mizuno

doi:10.1002/anie.200500491

Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide

Yoshinao Nakagawa, Keigo Kamata, Miyuki Kotani, Kazuya Yamaguchi, Noritaka Mizuno

Research output: Contribution to journal › Article

159 Citations (Scopus)

Abstract

The bis(μ-hydroxo)-bridged dioxovanadium site in [γ-1,2-H ₂SiV₂W₁₀O₄₀]⁴ catalyzes the epoxidation of alkenes in the presence of only one equivalent of H ₂O₂ with a high yield of epoxide, high efficiency of H₂O₂ utilization, unusual regioselectivity, and unprecedented diastereoselectivity (see picture). (Chemical Equation Presented)

Original language	English
Pages (from-to)	5136-5141
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	32
DOIs	https://doi.org/10.1002/anie.200500491
Publication status	Published - 2005 Aug 12
Externally published	Yes

Keywords

Alkenes
Epoxidation
Hydrogen peroxide
Polyoxometalates
Vanadium

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.200500491

Fingerprint Dive into the research topics of 'Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide'. Together they form a unique fingerprint.

Cite this

Nakagawa, Y., Kamata, K., Kotani, M., Yamaguchi, K., & Mizuno, N. (2005). Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide. Angewandte Chemie - International Edition, 44(32), 5136-5141. https://doi.org/10.1002/anie.200500491

@article{452546c650e2490fbb52e5f080b3ff95,

title = "Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide",

abstract = "The bis(μ-hydroxo)-bridged dioxovanadium site in [γ-1,2-H 2SiV2W10O40]4 catalyzes the epoxidation of alkenes in the presence of only one equivalent of H 2O2 with a high yield of epoxide, high efficiency of H2O2 utilization, unusual regioselectivity, and unprecedented diastereoselectivity (see picture). (Chemical Equation Presented)",

keywords = "Alkenes, Epoxidation, Hydrogen peroxide, Polyoxometalates, Vanadium",

author = "Yoshinao Nakagawa and Keigo Kamata and Miyuki Kotani and Kazuya Yamaguchi and Noritaka Mizuno",

year = "2005",

month = aug,

day = "12",

doi = "10.1002/anie.200500491",

language = "English",

volume = "44",

pages = "5136--5141",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "32",

}

TY - JOUR

T1 - Polyoxovanadometalate-catalyzed selective epoxidation of alkenes with hydrogen peroxide

AU - Nakagawa, Yoshinao

AU - Kamata, Keigo

AU - Kotani, Miyuki

AU - Yamaguchi, Kazuya

AU - Mizuno, Noritaka

PY - 2005/8/12

Y1 - 2005/8/12

N2 - The bis(μ-hydroxo)-bridged dioxovanadium site in [γ-1,2-H 2SiV2W10O40]4 catalyzes the epoxidation of alkenes in the presence of only one equivalent of H 2O2 with a high yield of epoxide, high efficiency of H2O2 utilization, unusual regioselectivity, and unprecedented diastereoselectivity (see picture). (Chemical Equation Presented)

AB - The bis(μ-hydroxo)-bridged dioxovanadium site in [γ-1,2-H 2SiV2W10O40]4 catalyzes the epoxidation of alkenes in the presence of only one equivalent of H 2O2 with a high yield of epoxide, high efficiency of H2O2 utilization, unusual regioselectivity, and unprecedented diastereoselectivity (see picture). (Chemical Equation Presented)

KW - Alkenes

KW - Epoxidation

KW - Hydrogen peroxide

KW - Polyoxometalates

KW - Vanadium

UR - http://www.scopus.com/inward/record.url?scp=23944434404&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=23944434404&partnerID=8YFLogxK

U2 - 10.1002/anie.200500491

DO - 10.1002/anie.200500491

M3 - Article

C2 - 16007715

AN - SCOPUS:23944434404

VL - 44

SP - 5136

EP - 5141

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 32

ER -