Polymer support assisted selective functionalization of Azoles using a palladium-catalyzed coupling reaction

Yoshinori Kondo, Takashi Komine, Takao Sakamoto

Research output: Contribution to journalArticlepeer-review

117 Citations (Scopus)

Abstract

(matrix presented) Regioselective palladium-catalyzed monoarylation of azoles was achieved using iodobenzoate immobilized on an insoluble polymer support. The positional selectivity for the coupling reaction was dramatically influenced by the presence of Cul. No diarylation was observed in either case. Unsymmetrical diarylation was also obtained with the polymer support using sequential coupling reactions.

Original languageEnglish
Pages (from-to)3111-3113
Number of pages3
JournalOrganic letters
Volume2
Issue number20
DOIs
Publication statusPublished - 2000 Oct 5

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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