Polymer support assisted selective functionalization of Azoles using a palladium-catalyzed coupling reaction

Yoshinori Kondo; Takashi Komine; Takao Sakamoto

doi:10.1021/ol000183u

Polymer support assisted selective functionalization of Azoles using a palladium-catalyzed coupling reaction

Yoshinori Kondo, Takashi Komine, Takao Sakamoto

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

118 Citations (Scopus)

Abstract

(matrix presented) Regioselective palladium-catalyzed monoarylation of azoles was achieved using iodobenzoate immobilized on an insoluble polymer support. The positional selectivity for the coupling reaction was dramatically influenced by the presence of Cul. No diarylation was observed in either case. Unsymmetrical diarylation was also obtained with the polymer support using sequential coupling reactions.

Original language	English
Pages (from-to)	3111-3113
Number of pages	3
Journal	Organic letters
Volume	2
Issue number	20
DOIs	https://doi.org/10.1021/ol000183u
Publication status	Published - 2000 Oct 5

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol000183u

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title = "Polymer support assisted selective functionalization of Azoles using a palladium-catalyzed coupling reaction",

abstract = "(matrix presented) Regioselective palladium-catalyzed monoarylation of azoles was achieved using iodobenzoate immobilized on an insoluble polymer support. The positional selectivity for the coupling reaction was dramatically influenced by the presence of Cul. No diarylation was observed in either case. Unsymmetrical diarylation was also obtained with the polymer support using sequential coupling reactions.",

author = "Yoshinori Kondo and Takashi Komine and Takao Sakamoto",

year = "2000",

month = oct,

day = "5",

doi = "10.1021/ol000183u",

language = "English",

volume = "2",

pages = "3111--3113",

journal = "Organic Letters",

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publisher = "American Chemical Society",

number = "20",

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TY - JOUR

T1 - Polymer support assisted selective functionalization of Azoles using a palladium-catalyzed coupling reaction

AU - Kondo, Yoshinori

AU - Komine, Takashi

AU - Sakamoto, Takao

PY - 2000/10/5

Y1 - 2000/10/5

N2 - (matrix presented) Regioselective palladium-catalyzed monoarylation of azoles was achieved using iodobenzoate immobilized on an insoluble polymer support. The positional selectivity for the coupling reaction was dramatically influenced by the presence of Cul. No diarylation was observed in either case. Unsymmetrical diarylation was also obtained with the polymer support using sequential coupling reactions.

AB - (matrix presented) Regioselective palladium-catalyzed monoarylation of azoles was achieved using iodobenzoate immobilized on an insoluble polymer support. The positional selectivity for the coupling reaction was dramatically influenced by the presence of Cul. No diarylation was observed in either case. Unsymmetrical diarylation was also obtained with the polymer support using sequential coupling reactions.

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U2 - 10.1021/ol000183u

DO - 10.1021/ol000183u

M3 - Article

AN - SCOPUS:0010597557

VL - 2

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EP - 3113

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 20

ER -

Polymer support assisted selective functionalization of Azoles using a palladium-catalyzed coupling reaction

Abstract

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