TY - JOUR
T1 - Poly[bis(phenethyl-ammonium) [di-bromido-plumbate(II)]-di-μ-bromido]]
AU - Shibuya, Kengo
AU - Koshimizu, Masanori
AU - Nishikido, Fumihiko
AU - Saito, Haruo
AU - Kishimoto, Shunji
N1 - Copyright:
Copyright 2010 Elsevier B.V., All rights reserved.
PY - 2009
Y1 - 2009
N2 - Crystals of the title compound, {(C6H5C 2H4NH3)2[PbBr4]} n , were grown at room temperature from a solution in N,N-dimethyl-formamide (DMF) using nitro-methane as the poor solvent. This perovskite-type organic-inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr6 octa-hedra separated by bilayers of phenethyl-ammonium cations. The octa-hedra are rotated and tilted due to N- H⋯Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetra-chloridoplumbate (C6H5C 2H4NH3)2[PbCl4].
AB - Crystals of the title compound, {(C6H5C 2H4NH3)2[PbBr4]} n , were grown at room temperature from a solution in N,N-dimethyl-formamide (DMF) using nitro-methane as the poor solvent. This perovskite-type organic-inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr6 octa-hedra separated by bilayers of phenethyl-ammonium cations. The octa-hedra are rotated and tilted due to N- H⋯Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetra-chloridoplumbate (C6H5C 2H4NH3)2[PbCl4].
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U2 - 10.1107/S160053680903712X
DO - 10.1107/S160053680903712X
M3 - Article
C2 - 21578085
AN - SCOPUS:70449458866
VL - 65
SP - m1323-m1324
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 11
ER -