Polarization switching behavior of one-axis-oriented lead zirconate titanate films fabricated on metal oxide nanosheet layer

Hiroshi Uchida, Daichi Ichinose, Takahisa Shiraishi, Hiromi Shima, Takanori Kiguchi, Akihiko Akama, Ken Nishida, Toyohiko J. Konno, Hiroshi Funakubo

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1 Citation (Scopus)

Abstract

For the application of electronic devices using ferroelectric/piezoelectric components, one-axis-oriented tetragonal Pb(Zr0.40Ti0.60)O3 (PZT) films with thicknesses of up to 1 μm were fabricated with the aid of a Ca2Nb3O10 nanosheet (ns-CN) template for preferential crystal growth for evaluating their polarization switching behavior. The ns-CN template was supported on ubiquitous silicon (Si) wafer by a simple dip coating technique, followed by the repetitive chemical solution deposition (CSD) of PZT films. The PZT films were grown successfully with preferential crystal orientation of PZT(100) up to the thickness of 1020 nm. The (100)-oriented PZT film with >1 μm thickness exhibited unique polarization behavior of ferroelectric polarization, i.e., a marked increase in remanent polarization (Pr) up to approximately 40 μC/cm2 induced by domain switching under high electric field, whereas the film with a lower thickness showed only a lower Pr of approximately 11 μC/cm2 even under a high electric field. The ferroelectric property of the (100)-oriented PZT film after domain switching on ns-CN/Pt/Si can be comparable to those of (001)/(100)-oriented epitaxial PZT films.

Original languageEnglish
Article number10PF10
JournalJapanese journal of applied physics
Volume56
Issue number10
DOIs
Publication statusPublished - 2017 Oct

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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