Abstract
A platinum(II) complex with organic radical ligand p-NNpy (=2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is synthesized. X-ray crystallographic analysis revealed that it has a square-planer four-coordinate anionic structure with formula of [Pt(p-NNpy)Cl3]-. Paramagnetic behavior which correspond to S=1/2 was observed with weak intermolecular antiferromagnetic interaction in the temperature range of 2-300 K. The structure, magnetic property and spectroscopic data will be reported.
Original language | English |
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Pages (from-to) | 355-356 |
Number of pages | 2 |
Journal | Synthetic Metals |
Volume | 135-136 |
DOIs | |
Publication status | Published - 2003 Apr 4 |
Externally published | Yes |
Keywords
- Electron spin resonance
- Magnetic measurement
- UV-vis-NIR absorption
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics
- Mechanics of Materials
- Mechanical Engineering
- Metals and Alloys
- Materials Chemistry