Platinum(II) complex with S=1/2 organic radical ligand

F. Iwahori; H. Miyasaka; T. Ishii; K. I. Sugiura; M. Yamashita

doi:10.1016/S0379-6779(02)00555-6

Platinum(II) complex with S=1/2 organic radical ligand

F. Iwahori, H. Miyasaka, T. Ishii, K. I. Sugiura, M. Yamashita

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

A platinum(II) complex with organic radical ligand p-NNpy (=2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is synthesized. X-ray crystallographic analysis revealed that it has a square-planer four-coordinate anionic structure with formula of [Pt(p-NNpy)Cl₃]^-. Paramagnetic behavior which correspond to S=1/2 was observed with weak intermolecular antiferromagnetic interaction in the temperature range of 2-300 K. The structure, magnetic property and spectroscopic data will be reported.

Original language	English
Pages (from-to)	355-356
Number of pages	2
Journal	Synthetic Metals
Volume	135-136
DOIs	https://doi.org/10.1016/S0379-6779(02)00555-6
Publication status	Published - 2003 Apr 4
Externally published	Yes

Keywords

Electron spin resonance
Magnetic measurement
UV-vis-NIR absorption

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/S0379-6779(02)00555-6

Cite this

@article{421058527d5e40d68f7c7d0dab882bd9,

title = "Platinum(II) complex with S=1/2 organic radical ligand",

abstract = "A platinum(II) complex with organic radical ligand p-NNpy (=2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is synthesized. X-ray crystallographic analysis revealed that it has a square-planer four-coordinate anionic structure with formula of [Pt(p-NNpy)Cl3]-. Paramagnetic behavior which correspond to S=1/2 was observed with weak intermolecular antiferromagnetic interaction in the temperature range of 2-300 K. The structure, magnetic property and spectroscopic data will be reported.",

keywords = "Electron spin resonance, Magnetic measurement, UV-vis-NIR absorption",

author = "F. Iwahori and H. Miyasaka and T. Ishii and Sugiura, {K. I.} and M. Yamashita",

year = "2003",

month = apr,

day = "4",

doi = "10.1016/S0379-6779(02)00555-6",

language = "English",

volume = "135-136",

pages = "355--356",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Platinum(II) complex with S=1/2 organic radical ligand

AU - Iwahori, F.

AU - Miyasaka, H.

AU - Ishii, T.

AU - Sugiura, K. I.

AU - Yamashita, M.

PY - 2003/4/4

Y1 - 2003/4/4

N2 - A platinum(II) complex with organic radical ligand p-NNpy (=2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is synthesized. X-ray crystallographic analysis revealed that it has a square-planer four-coordinate anionic structure with formula of [Pt(p-NNpy)Cl3]-. Paramagnetic behavior which correspond to S=1/2 was observed with weak intermolecular antiferromagnetic interaction in the temperature range of 2-300 K. The structure, magnetic property and spectroscopic data will be reported.

AB - A platinum(II) complex with organic radical ligand p-NNpy (=2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) is synthesized. X-ray crystallographic analysis revealed that it has a square-planer four-coordinate anionic structure with formula of [Pt(p-NNpy)Cl3]-. Paramagnetic behavior which correspond to S=1/2 was observed with weak intermolecular antiferromagnetic interaction in the temperature range of 2-300 K. The structure, magnetic property and spectroscopic data will be reported.

KW - Electron spin resonance

KW - Magnetic measurement

KW - UV-vis-NIR absorption

UR - http://www.scopus.com/inward/record.url?scp=6344288043&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=6344288043&partnerID=8YFLogxK

U2 - 10.1016/S0379-6779(02)00555-6

DO - 10.1016/S0379-6779(02)00555-6

M3 - Article

AN - SCOPUS:6344288043

VL - 135-136

SP - 355

EP - 356

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

ER -

Platinum(II) complex with S=1/2 organic radical ligand

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this