Platinum- and palladium-catalyzed sequential reactions: Regioselective synthesis of 9-fluorenylidenes from 9-ethynylfluoren-9-yl carboxylates and furans

Koji Miki, Yoshinori Senda, Toshiyuki Kowada, Kouichi Ohe

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The transformation of 9-acyloxy-9-ethynylfluorene and furans with platinum and palladium co-catalysts gave 9-fluorenylidenes in excellent yields with high regioselectivity in a one-pot manner.

Original languageEnglish
Pages (from-to)1937-1940
Number of pages4
JournalSynlett
Issue number12
DOIs
Publication statusPublished - 2009 Jul 1
Externally publishedYes

Keywords

  • Carbene
  • Fluorene
  • Palladium
  • Platinum
  • Ring opening

ASJC Scopus subject areas

  • Organic Chemistry

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