Plasma-Induced Chemisorption of Nitrogen and Its Chemical Reactivity on Alumina

Kimio Kunimori, Takashi Kuriyama, Shin Ichi Ito, Satoshi Kameoka

Research output: Contribution to journalArticlepeer-review

15 Citations (Scopus)

Abstract

Nitrogen was chemisorbed on an alumina (Al2O3) surface by plasma discharge of N2, and the chemical behavior of chemisorbed nitrogen was studied by temperature-programmed desorption (TPD) and infrared (IR) spectroscopy. Molecular nitrogen N2(ad) chemisorbed on an Al2O3 surface showed a high reactivity with hydrogen even at room temperature, if Pt is present on the Al2O3 surface. Hydrogenated species, NH x (ad) (x=1 or 2) and NH3(ad) were formed on the Al2O3 surface as evidenced by IR spectroscopy. It is suggested that hydrogen spill-over from the Pt surface onto the Al2O3 catalyst plays an important role in the mechanism of hydrogenation reaction.

Original languageEnglish
Number of pages1
JournalJapanese journal of applied physics
Volume33
Issue number7S
DOIs
Publication statusPublished - 1994 Jul
Externally publishedYes

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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