Plasma-induced chemisorption of nitrogen and hydrogen on alumina-supported platinum catalysts

S. Kameoka, S. Ito, K. Kunimori

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Nitrogen was chemisorbed on a Pt/Al2O3 catalyst by a plasma discharge of N2, and the chemical reactivity of the chemisorbed nitrogen with hydrogen was studied by temperature-programmed desorption (TPD) and infrared (IR) spectroscopy. The adsorbed nitrogen was desorbed at around 200°C by TPD, and a part of the adsorbed species was reacted with hydrogen to form NH3. IR spectroscopy showed an absorption band at 2260 cm−1, which was assigned to N-N streching of molecular N2(a) chemisorbed mainly on the Al2O3 support. It was suggested that the N2(a) reacted with the spiltover hydrogen from Pt surface even at room temperature.

Original languageEnglish
Pages (from-to)257-260
Number of pages4
JournalStudies in Surface Science and Catalysis
Volume77
Issue numberC
DOIs
Publication statusPublished - 1993 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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