Photorefractive polysilanes functionalized with a nonlinear optical chromophore

Eric Hendrickx, David Van Steenwinckel, André Persoons, Akira Watanabe

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

We have prepared various polysilane copolymers that were functionalized with the nonlinear optical chromophore N-methyl-p-nitroaniline. The glass transition temperature of the polysilanes was adjusted to room temperature by copolymerization of methylphenyldichlorosilane and n-hexylmethyldichlorosilane. Asymmetric two-beam coupling was observed at 633 nm, and a gain coefficient of 18 cm-1 was measured at an externally applied field of 48 V μm-1.

Original languageEnglish
Pages (from-to)2232-2238
Number of pages7
JournalMacromolecules
Volume32
Issue number7
DOIs
Publication statusPublished - 1999 Apr 6

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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