Photopolymerization of the diacetylene nucleobase monolayers controlled by triplex formation

Jin Matsumoto, Kuniharu Ijiro, Masatsugu Shimomura

    Research output: Contribution to journalArticle

    2 Citations (Scopus)

    Abstract

    Pressure-area isotherms of ternary component monolayers of nucleobase amphiphiles, octadecylcytosine (C18-Cyt) and diacetylene-containing adenine and thymine amphiphiles (DA-Ade, DA-Thy), were changed by addition of oligonucleotides, d(GT)15 or d(GGT)10, in the water subphase. Photopolymerization of diacetylene in the monolayer was strongly suppressed on the oligonucleotide subphase. This suggests that the oligonucleotide can act as a template for the diacetylene monomer arrangement via complementary hydrogen bonding at the air-water interface.

    Original languageEnglish
    Pages (from-to)33-36
    Number of pages4
    JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
    Volume371
    DOIs
    Publication statusPublished - 2001 Jan 1

    Keywords

    • Base trimer formation
    • Diacetylene
    • Molecular recognition
    • Nucleobase monolayer
    • Photopolymerization
    • Template polymerization

    ASJC Scopus subject areas

    • Condensed Matter Physics

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