Photon-stimulated desorption of h+ ions from oxidized si(111) surfaces

Yuji Takakuwa, Michio Niwano, Masafumi Nogawa, Hitoshi Katakura, Satoshi Matsuyoshi, Hiroyuki Ishida, Hiroo Kato, Nobuo Miyamoto

Research output: Contribution to journalArticle

7 Citations (Scopus)


Photon-stimulated desorption (PSD) experiments on oxidized Si(111) surfaces were performed to study the adsorption of hydrogen at the SiO2/Si(111) interface using synchrotron radiation. H+ is found to be the only ion product desorbing in significant quantities from the oxidized surfaces at photon energies above 20 eV. PSD spectra of H+ ions, i.e., the H+ ion desorption yield as a function of photon energy, exhibit two peaks at 23 eV and 33 eV. These peaks are interpreted in terms of Si-H bond and O-H bond breaking in a Si-H and Si-OH complex, respectively. The observed dependence of the H+ ion yield on oxidation temperature implies that the peak at 23 eV originates from hydrogen atoms adsorbed onto the so-called Pb centers at the SiO2/Si(111) interface. A comparison between the PSD and the total photoelectric yield spectra, the latter of which corresponds to the photoabsorption spectrum, is also made.

Original languageEnglish
Pages (from-to)2581-2586
Number of pages6
JournalJapanese journal of applied physics
Issue number12 R
Publication statusPublished - 1989 Dec


  • Hydrogen adsorption
  • Hydrogen ion
  • Oxidation
  • PSD
  • Pb center
  • Si(111) surface
  • Si02/Si interface
  • Synchrotron radiation

ASJC Scopus subject areas

  • Engineering(all)
  • Physics and Astronomy(all)

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    Takakuwa, Y., Niwano, M., Nogawa, M., Katakura, H., Matsuyoshi, S., Ishida, H., Kato, H., & Miyamoto, N. (1989). Photon-stimulated desorption of h+ ions from oxidized si(111) surfaces. Japanese journal of applied physics, 28(12 R), 2581-2586.