Photoion yield curves of Dy@C82 in the vacuum UV region

Koichiro Mitsuke; Takanori Mori; Junkei Kou; Yusuke Haruyama; Yasuhiro Takabayashi; Yoshihiro Kubozono

doi:10.1016/j.ijms.2005.02.001

Photoion yield curves of Dy@C₈₂ in the vacuum UV region

Koichiro Mitsuke, Takanori Mori, Junkei Kou, Yusuke Haruyama, Yasuhiro Takabayashi, Yoshihiro Kubozono

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The photoion yield curves for Dy@C₈₂^z+ (z = 1 and 2) from Dy@C₈₂ are measured by using synchrotron radiation in the photon energy range from 24.5 to 39.5 eV. Correction has been made to compensate the effect of transient change of the density of Dy@C₈₂ in the interaction region, with the help of the yield curve of C₆₀ ^z+ produced from C₆₀ remaining as a trace impurity in the sample. The yield of Dy@C₈₂⁺ exhibits a gradually descending curve with a flat region at 30-33 eV, similarly to the yield curve of C₆₀⁺ from C₆₀. The total photoabsorption cross section of Dy@C₈₂ was evaluated to be (1.2 ± 0.4) × 10^-20 m² at the photon energy of 39.5 eV.

Original language	English
Pages (from-to)	121-125
Number of pages	5
Journal	International Journal of Mass Spectrometry
Volume	243
Issue number	2
DOIs	https://doi.org/10.1016/j.ijms.2005.02.001
Publication status	Published - 2005 May 15
Externally published	Yes

Keywords

Dy@C
Metal endohedral fullerenes
Metallofullerenes
Photoabsorption
Vacuum ultraviolet

ASJC Scopus subject areas

Instrumentation
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry

Access to Document

10.1016/j.ijms.2005.02.001

Cite this

@article{855408e4486b4914a1c1b5367d006870,

title = "Photoion yield curves of Dy@C82 in the vacuum UV region",

abstract = "The photoion yield curves for Dy@C82z+ (z = 1 and 2) from Dy@C82 are measured by using synchrotron radiation in the photon energy range from 24.5 to 39.5 eV. Correction has been made to compensate the effect of transient change of the density of Dy@C82 in the interaction region, with the help of the yield curve of C60 z+ produced from C60 remaining as a trace impurity in the sample. The yield of Dy@C82+ exhibits a gradually descending curve with a flat region at 30-33 eV, similarly to the yield curve of C60+ from C60. The total photoabsorption cross section of Dy@C82 was evaluated to be (1.2 ± 0.4) × 10-20 m2 at the photon energy of 39.5 eV.",

keywords = "Dy@C, Metal endohedral fullerenes, Metallofullerenes, Photoabsorption, Vacuum ultraviolet",

author = "Koichiro Mitsuke and Takanori Mori and Junkei Kou and Yusuke Haruyama and Yasuhiro Takabayashi and Yoshihiro Kubozono",

note = "Funding Information: The authors are grateful to Professor S. Hino in Chiba University for valuable discussion and suggestions. This work has been supported by a Grant-in-Aid for Scientific Research (Grant no. 14340188) from the Ministry of Education, Science, Sports, and Culture, Japan, and by a grant for scientific research from Research Foundation for Opto-Science and Technology.",

year = "2005",

month = may,

day = "15",

doi = "10.1016/j.ijms.2005.02.001",

language = "English",

volume = "243",

pages = "121--125",

journal = "International Journal of Mass Spectrometry and Ion Processes",

issn = "1387-3806",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Photoion yield curves of Dy@C82 in the vacuum UV region

AU - Mitsuke, Koichiro

AU - Mori, Takanori

AU - Kou, Junkei

AU - Haruyama, Yusuke

AU - Takabayashi, Yasuhiro

AU - Kubozono, Yoshihiro

N1 - Funding Information: The authors are grateful to Professor S. Hino in Chiba University for valuable discussion and suggestions. This work has been supported by a Grant-in-Aid for Scientific Research (Grant no. 14340188) from the Ministry of Education, Science, Sports, and Culture, Japan, and by a grant for scientific research from Research Foundation for Opto-Science and Technology.

PY - 2005/5/15

Y1 - 2005/5/15

N2 - The photoion yield curves for Dy@C82z+ (z = 1 and 2) from Dy@C82 are measured by using synchrotron radiation in the photon energy range from 24.5 to 39.5 eV. Correction has been made to compensate the effect of transient change of the density of Dy@C82 in the interaction region, with the help of the yield curve of C60 z+ produced from C60 remaining as a trace impurity in the sample. The yield of Dy@C82+ exhibits a gradually descending curve with a flat region at 30-33 eV, similarly to the yield curve of C60+ from C60. The total photoabsorption cross section of Dy@C82 was evaluated to be (1.2 ± 0.4) × 10-20 m2 at the photon energy of 39.5 eV.

AB - The photoion yield curves for Dy@C82z+ (z = 1 and 2) from Dy@C82 are measured by using synchrotron radiation in the photon energy range from 24.5 to 39.5 eV. Correction has been made to compensate the effect of transient change of the density of Dy@C82 in the interaction region, with the help of the yield curve of C60 z+ produced from C60 remaining as a trace impurity in the sample. The yield of Dy@C82+ exhibits a gradually descending curve with a flat region at 30-33 eV, similarly to the yield curve of C60+ from C60. The total photoabsorption cross section of Dy@C82 was evaluated to be (1.2 ± 0.4) × 10-20 m2 at the photon energy of 39.5 eV.

KW - Dy@C

KW - Metal endohedral fullerenes

KW - Metallofullerenes

KW - Photoabsorption

KW - Vacuum ultraviolet

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