Photoinduced Near-Infrared Absorption in an M-X Chain Complex [Pt(en)2l[Pt(en)2Cl2](ClO4)4, en=ethylenediamine

Noritaka Kuroda, Motoki Ito, Yuichiro Nishina, Masahiro Yamashita

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

The near-infrared absorption spectrum has been measured in [Pt(en)2][Pt(en)2Cl2](0104)4, (en)=ethylenediamine, irradiated with the 488 nm beam of an Ar-ion laser. In addition to the well-established intragap bands A around 1.6 eV and B around 2.0 eV, a broad band B’ is found to overlap the B band and be spread beyond 2.3 eV. No bands can be found at photon energies down to 1.2 eV below the A band. The results are discussed in relation to the �two-band� theory for polarons and solitons by Tinka-Gammel and coworkers (Phys. Rev. B45 (1992) 6435).

Original languageEnglish
Pages (from-to)2237-2240
Number of pages4
JournalJournal of the Physical Society of Japan
Volume62
Issue number7
DOIs
Publication statusPublished - 1993 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Fingerprint Dive into the research topics of 'Photoinduced Near-Infrared Absorption in an M-X Chain Complex [Pt(en)<sub>2</sub>l[Pt(en)<sub>2</sub>Cl<sub>2</sub>](ClO<sub>4</sub>)<sub>4</sub>, en=ethylenediamine'. Together they form a unique fingerprint.

  • Cite this