Photoinduced Membrane Potential across Poly(vinyl chloride) Membrane Entrapping Spirobenzopyran Derivative

Jun Ichi Anzai; Yasushi Hasebe; Akihiko Ueno; Tetsuo Osa

doi:10.1295/koron.43.683

Photoinduced Membrane Potential across Poly(vinyl chloride) Membrane Entrapping Spirobenzopyran Derivative

Jun Ichi Anzai, Yasushi Hasebe, Akihiko Ueno, Tetsuo Osa

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A spirobenzopyran derivative (1′-hexadecy1-3′,3′-dimethy1-6-nitrospiro[2H-1-benzopyran-2,2′-indolinen]) was immobilized into poly(vinyl chloride) membrane in order to study the photo-response of the membrane potential. UV light irradiation induced membrane potential changes of more than 100 mV with a response time of ca. 1 min. The photoinduced potential changes were larger in the lower ionic concentration region. Photo-response was also observed when no concentration gradient of electrolyte between the two solutions existed; this was explained based on the formation of asymmetric membrane under UV light irradiation. Photo-response of the membrane potential was enhanced in the slightly acidic region, suggesting an important role of the protonated form of opened spirobenzopyran in determining the membrane potential.

Original language	English
Pages (from-to)	683-689
Number of pages	7
Journal	KOBUNSHI RONBUNSHU
Volume	43
Issue number	10
DOIs	https://doi.org/10.1295/koron.43.683
Publication status	Published - 1986
Externally published	Yes

Keywords

Asymmetric Membrane
Membrane Potential
Photoirradiation
Poly(vinyl chloride)
Spirobenzopyran

ASJC Scopus subject areas

Chemical Engineering (miscellaneous)
Materials Science (miscellaneous)
Environmental Science(all)
Polymers and Plastics

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10.1295/koron.43.683

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title = "Photoinduced Membrane Potential across Poly(vinyl chloride) Membrane Entrapping Spirobenzopyran Derivative",

abstract = "A spirobenzopyran derivative (1′-hexadecy1-3′,3′-dimethy1-6-nitrospiro[2H-1-benzopyran-2,2′-indolinen]) was immobilized into poly(vinyl chloride) membrane in order to study the photo-response of the membrane potential. UV light irradiation induced membrane potential changes of more than 100 mV with a response time of ca. 1 min. The photoinduced potential changes were larger in the lower ionic concentration region. Photo-response was also observed when no concentration gradient of electrolyte between the two solutions existed; this was explained based on the formation of asymmetric membrane under UV light irradiation. Photo-response of the membrane potential was enhanced in the slightly acidic region, suggesting an important role of the protonated form of opened spirobenzopyran in determining the membrane potential.",

keywords = "Asymmetric Membrane, Membrane Potential, Photoirradiation, Poly(vinyl chloride), Spirobenzopyran",

author = "Anzai, {Jun Ichi} and Yasushi Hasebe and Akihiko Ueno and Tetsuo Osa",

year = "1986",

doi = "10.1295/koron.43.683",

language = "English",

volume = "43",

pages = "683--689",

journal = "Kobunshi Ronbunshu",

issn = "0386-2186",

publisher = "Society of Polymer Science",

number = "10",

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T1 - Photoinduced Membrane Potential across Poly(vinyl chloride) Membrane Entrapping Spirobenzopyran Derivative

AU - Anzai, Jun Ichi

AU - Hasebe, Yasushi

AU - Ueno, Akihiko

AU - Osa, Tetsuo

PY - 1986

Y1 - 1986

N2 - A spirobenzopyran derivative (1′-hexadecy1-3′,3′-dimethy1-6-nitrospiro[2H-1-benzopyran-2,2′-indolinen]) was immobilized into poly(vinyl chloride) membrane in order to study the photo-response of the membrane potential. UV light irradiation induced membrane potential changes of more than 100 mV with a response time of ca. 1 min. The photoinduced potential changes were larger in the lower ionic concentration region. Photo-response was also observed when no concentration gradient of electrolyte between the two solutions existed; this was explained based on the formation of asymmetric membrane under UV light irradiation. Photo-response of the membrane potential was enhanced in the slightly acidic region, suggesting an important role of the protonated form of opened spirobenzopyran in determining the membrane potential.

AB - A spirobenzopyran derivative (1′-hexadecy1-3′,3′-dimethy1-6-nitrospiro[2H-1-benzopyran-2,2′-indolinen]) was immobilized into poly(vinyl chloride) membrane in order to study the photo-response of the membrane potential. UV light irradiation induced membrane potential changes of more than 100 mV with a response time of ca. 1 min. The photoinduced potential changes were larger in the lower ionic concentration region. Photo-response was also observed when no concentration gradient of electrolyte between the two solutions existed; this was explained based on the formation of asymmetric membrane under UV light irradiation. Photo-response of the membrane potential was enhanced in the slightly acidic region, suggesting an important role of the protonated form of opened spirobenzopyran in determining the membrane potential.

KW - Asymmetric Membrane

KW - Membrane Potential

KW - Photoirradiation

KW - Poly(vinyl chloride)

KW - Spirobenzopyran

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ER -

Photoinduced Membrane Potential across Poly(vinyl chloride) Membrane Entrapping Spirobenzopyran Derivative

Abstract

Keywords

ASJC Scopus subject areas

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