Photodissociation of formic acid: Internal state distribution of OH fragment

Takayuki Ebata, Asuka Fujii, Taro Amano, Mitsuo Ito

Research output: Contribution to journalArticlepeer-review

25 Citations (Scopus)

Abstract

The internal state distribution of the nascent OH fragment produced by the photodissociation of formic acid monomer has been investigated. Formic acid is photolyzed at several wavelengths (220-250 nm) corresponding to the S1(nπ*) ← S0 transition. The ejected OH fragment, monitored by laser-induced fluorescence, is vibrationally and rotationally cold. The internal energies of the OH fragments and also the ratio of the two spin sublevels 2Π1/2/2Π3/2 decrease with decreasing the photodissociation energy.

Original languageEnglish
Pages (from-to)6095-6097
Number of pages3
JournalJournal of physical chemistry
Volume91
Issue number24
DOIs
Publication statusPublished - 1987

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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