Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex. Generation of a Novel Te-Si-Fe Three-membered Cyclic Intermediate

Hiroshi Okada, Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The tellurosilyliron complex Cp*(CO)2FeSiMe 2TePh (1) was synthesized by treatment of Cp*(CO) 2FeSiMe2Cl with LiTePh. Irradiation of complex 1 and acetone in toluene led to dissociation of a CO ligand and insertion of acetone into the silicon-tellurium bond to afford the five-membered metallacycle Cp*(CO)Fe{K2(Si,Te)-Me2SiOCMe2TePh}.

Original languageEnglish
Pages (from-to)876-877
Number of pages2
JournalChemistry Letters
Volume32
Issue number9
DOIs
Publication statusPublished - 2003 Sep 5

ASJC Scopus subject areas

  • Chemistry(all)

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