Photochemical reaction using aminobenzenethiol single molecular junction

Y. Matsuzawa, S. Kaneko, S. Fujii, T. Nishino, M. Kiguchi, K. Tsukagoshi

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

Photo-induced chemical reaction of p-aminobenzenthiol (ABT) was investigated using the lithographically fabricated mechanically controllable break junction (MCBJ). The ABT single-molecule junction was formed at the nanogap of the MCBJ and the formation was confirmed by the electronic transport measurement including current versus bias voltage characteristics. Light irradiation at the nanogap revealed that ABT molecules were subject to photo-induced dimerization, which was confirmed by measuring SERS spectrum. In addition, we tuned the gap size using MCBJ technique and demonstrated that the photo-induced dimerization was absent for the molecules at the wide gap.

Original languageEnglish
Pages (from-to)137-141
Number of pages5
Journale-Journal of Surface Science and Nanotechnology
Volume16
DOIs
Publication statusPublished - 2018 May 9
Externally publishedYes

Keywords

  • Photochemical reaction
  • Plasmon
  • Single molecular junction
  • Surface enhanced Raman scattering

ASJC Scopus subject areas

  • Biotechnology
  • Bioengineering
  • Condensed Matter Physics
  • Mechanics of Materials
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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