Photochemical behaviors of a tethered 1,3-diketone derivative studied by transient absorption and time-resolved EPR measurements

Atsushi Kobayashi, Minoru Yamaji, Satoru Nakajima, Kimio Akiyama, Shozo Tero-Kubota, Shin Ichiro Kato, Yosuke Nakamura

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Molecular structures of acetyltetralone (AT) in the enol form were investigated based on the photochemical features in comparison with that of benzoylacetone. Laser flash photolysis of AT in fluid media showed the formation of the triplet state which was characterized by time-resolved electron paramagnetic resonance measurements. From these results, the molecular structure of AT in the enol form was concluded to be endocyclic with the C-C double bond in the tetralone moiety.

Original languageEnglish
Pages (from-to)101-105
Number of pages5
JournalChemical Physics Letters
Volume555
DOIs
Publication statusPublished - 2013 Jan 3

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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