Photoabsorption spectra of CF3I and thermally dissociated CF3I near the C 1s, I 3d and F 1s ionisation thresholds

T. Tanaka, M. Hoshino, H. Kato, J. R. Harries, Y. Tamenori, K. Ueda, H. Tanaka

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

We report soft X-ray total ion yield and angular-resolved ion yield spectra of CF3I in the C 1s, I 3d and F 1s ionisation regions, and tentatively assign the observed electronic states. Anisotropy in ion yield is observed only for the C 1 s → σC - I*transition, indicating that the dipole moment for this transition is parallel to the C3v. The effusive source of CF3I is heated to 800 K to produce a mixture of CF3 and I, and the resulting spectra are compared to those recorded at room temperature.

Original languageEnglish
Pages (from-to)24-27
Number of pages4
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume164
Issue number1-3
DOIs
Publication statusPublished - 2008 Jul 1

Keywords

  • Core excitation
  • Gas phase
  • Ion-yield spectroscopy
  • Soft X-ray

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Radiation
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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