Photo-control of the magnetic properties of Dy(iii) and Ho(iii) homometal coordination polymers bridged by a diarylethene ligand

Goulven Cosquer, Masakazu Morimoto, Masahiro Irie, Ahmed Fetoh, Brian K. Breedlove, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

Two-dimensional Dy(iii) and Ho(iii) homometal coordination polymers containing the photochromic ligand 1,2-bis(5-carboxyl-2-methyl-3-thienyl)perfluorocyclopentene (DTE) with the general formula [Ln2(DTE)3(bipyridine)2(H2O)2]n (Ln = Dy and Ho) were obtained, and the magnetic properties of their open (Dy-o and Ho-o) and closed forms (Dy-c and Ho-c) were investigated. The Dy complexes exhibited slow magnetic relaxation without an external dc field. The magnetic properties of the Dy complexes were irreversibly affected by the conformation of the ligand. This journal is

Original languageEnglish
Pages (from-to)5996-6002
Number of pages7
JournalDalton Transactions
Volume44
Issue number13
DOIs
Publication statusPublished - 2015 Apr 7

ASJC Scopus subject areas

  • Inorganic Chemistry

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