Photo-control of the magnetic properties of Dy(iii) and Ho(iii) homometal coordination polymers bridged by a diarylethene ligand

Goulven Cosquer; Masakazu Morimoto; Masahiro Irie; Ahmed Fetoh; Brian K. Breedlove; Masahiro Yamashita

doi:10.1039/c4dt03093a

Photo-control of the magnetic properties of Dy(iii) and Ho(iii) homometal coordination polymers bridged by a diarylethene ligand

Goulven Cosquer, Masakazu Morimoto, Masahiro Irie, Ahmed Fetoh, Brian K. Breedlove, Masahiro Yamashita

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

Two-dimensional Dy(iii) and Ho(iii) homometal coordination polymers containing the photochromic ligand 1,2-bis(5-carboxyl-2-methyl-3-thienyl)perfluorocyclopentene (DTE) with the general formula [Ln₂(DTE)₃(bipyridine)₂(H₂O)₂]_n (Ln = Dy and Ho) were obtained, and the magnetic properties of their open (Dy-o and Ho-o) and closed forms (Dy-c and Ho-c) were investigated. The Dy complexes exhibited slow magnetic relaxation without an external dc field. The magnetic properties of the Dy complexes were irreversibly affected by the conformation of the ligand. This journal is

Original language	English
Pages (from-to)	5996-6002
Number of pages	7
Journal	Dalton Transactions
Volume	44
Issue number	13
DOIs	https://doi.org/10.1039/c4dt03093a
Publication status	Published - 2015 Apr 7

ASJC Scopus subject areas

Inorganic Chemistry

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AU - Cosquer, Goulven

AU - Morimoto, Masakazu

AU - Irie, Masahiro

AU - Fetoh, Ahmed

AU - Breedlove, Brian K.

AU - Yamashita, Masahiro

PY - 2015/4/7

Y1 - 2015/4/7

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Photo-control of the magnetic properties of Dy(iii) and Ho(iii) homometal coordination polymers bridged by a diarylethene ligand

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