Phenyl 2-amino-N,6-O-dibenzyl-2,3-N,O-carbonyl-2-deoxy-1-thio-Β-d- glucopyran-oside

Shino Manabe, Kazuyuki Ishii, Daisuke Hashizume, Yukishige Ito

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

In the crystal structure of the title compound, C27H 27NO5S, the pyran-ose ring adopts a 4C 1 chair conformation with puckering parameters Q = 0.639 (2) Å, θ = 174.11 (18) and φ = 256 (2)°. The presence of the 2,3-trans-oxazolidinone fixes the conformation of the pyran-ose ring. The phenyl group attached to the S atom and the benzyl group bonding to the N atom are each disordered over two positions with site occupancies of 0.624 (3):0.376 (3) and 0.526 (3):0.474 (3), respectively. An inter-molecular O - H⋯O hydrogen bond is observed.

Original languageEnglish
Pages (from-to)o1868
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number10
DOIs
Publication statusPublished - 2008
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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