Phase equilibria of the system Fe-Mg-Nd at 1076 K

Osamu Takeda, Toru H. Okabe, Yoshiaki Umetsu

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)

Abstract

Phase equilibria of the system Fe-Mg-Nd have been investigated in order to develop a new recycling process for Nd-Fe-B magnet scraps using molten Mg as the extraction medium. The phase relations between Fe-Nd alloy and Mg-Nd alloy were studied at 1076 K by isothermal equilibration experiments and composition analysis of the quenched samples. Liquid Mg-Nd alloy containing about 24 mol% Nd (65 mass% Nd) was found to be in equilibrium with both Nd2Fe 17 compound and iron solid solution. The results indicate that the Mg-Nd alloy with less than 24 mol% Nd is capable of extracting Nd from the Nd2Fe17 compound, and iron solid solution is formed after extraction. The results show the usefulness of directly extracting neodymium metal as a pure metal out of magnet scraps.

Original languageEnglish
Pages (from-to)206-213
Number of pages8
JournalJournal of Alloys and Compounds
Volume392
Issue number1-2
DOIs
Publication statusPublished - 2005 Apr 19

Keywords

  • Magnesium
  • Neodymium
  • Phase equilibrium
  • Rare earth magnet scrap
  • Recycling

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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