Phase equilibria of Fe-S-C ternary melts

Chao Wang, Jun Hirama, Tesuya Nagasaka, Shiro Ban-Ya

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Phase equilibria of Fe-S-C ternary melts have been studied to obtain fundamental knowledge on copper removal from liquid iron by FeS flux. Measurements were made to clarify the solubility of carbon and miscibility gap between iron and FeS melts at carbon saturation or unsaturation 1473 to 1873 K. In order to determine the interaction parameter in the Fe-C binary system, activity of iron in liquid alloys was measured by the distribution of iron between liquid iron and silver. It is concluded that interstitial model is applicable to express thermodynamic relations in this system. By this model, phase diagram and iso-activity contour of constituents were calculated.

Original languageEnglish
Pages (from-to)353-360
Number of pages8
JournalTetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan
Volume77
Issue number3
DOIs
Publication statusPublished - 1991 Jan 1

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Metals and Alloys
  • Materials Chemistry

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