Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges

Wenting Liang, Cheng Yang, Dayang Zhou, Hitoshi Haneoka, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Franca Castiglione, Andrea Mele, Fabrizio Caldera, Francesco Trotta, Yoshihisa Inoue

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL−1 in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z, Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E, Z)-isomers in the highest enantiomeric excesses in the gel state.

Original languageEnglish
Pages (from-to)3510-3512
Number of pages3
JournalChemical Communications
Volume49
Issue number34
DOIs
Publication statusPublished - 2013 Apr 2
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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    Liang, W., Yang, C., Zhou, D., Haneoka, H., Nishijima, M., Fukuhara, G., Mori, T., Castiglione, F., Mele, A., Caldera, F., Trotta, F., & Inoue, Y. (2013). Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges. Chemical Communications, 49(34), 3510-3512. https://doi.org/10.1039/c3cc40542g