Permittivity enhancement of transparent poly(vinylidene fluoride) nanocomposite films by loading titania-coated barium titanate nanoparticles

Jun Kanazawa, Tsuyoshi Kanamori, Masaki Sato, Haruyuki Ishii, Mikio Konno, Daisuke Nagao

Research output: Contribution to journalArticlepeer-review

Abstract

Barium titanate (BT) nanoparticles are coated by titania and modified by fluoroalkylsilane. The BT nanoparticles are incorporated into polyvinylidene fluoride (PVDF) films to obtain highly dielectric and transparent nanocomposite films at low filler loadings. Incorporation of BT nanoparticles having average sizes of 12 and 22 nm is performed. Incorporation of BT nanoparticles enhances the permittivity of PVDF films. Higher transparency of nanocomposite films is achieved by incorporating 12-nm nanoparticles compared to that by 22-nm nanoparticles. The polarisation mechanism in the nanocomposite films is examined using the Vo–Shi model. The result indicates that even a slight increase in the thickness of titania-coating layer on the BT nanoparticles increase the permittivity of the nanocomposite films. Comparison of the measured and calculated permittivities showed that the incorporation of BT nanoparticles coated with titania provides a practical approach to create transparent nanocomposite films having high permittivity. [Figure not available: see fulltext.].

Original languageEnglish
Article number186
JournalJournal of Nanoparticle Research
Volume20
Issue number7
DOIs
Publication statusPublished - 2018 Jul 1

Keywords

  • Barium titanate
  • Coating
  • Permittivity
  • Polymers
  • Thin film
  • Titania

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Atomic and Molecular Physics, and Optics
  • Modelling and Simulation
  • Materials Science(all)
  • Condensed Matter Physics

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