Pentaamminechlorogallium(III) dichloride

Hisanori Yamane, Yutaka Mikawa, Chiaki Yokoyama

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Crystals of the title compound, [Ga(NH3)5Cl]Cl 2, were prepared from 1-butyl-3-methylimidazolium chloride and GaCl3. The crystal structure is isotypic with [Al(NH 3)5Cl]Cl2 and other members of the series [M(NH3)5Cl]Cl2, with M = Cr, Co, Rh, Ir, Ru or Os. It consists of discrete cationic [Ga(NH3)5Cl] 2+ octahedra and Cl- anions arranged in motifs related to the K2PtCl6 structure type. In the cation, the Ga atom, one Cl atom and three N atoms are located on a mirror plane.

Original languageEnglish
Pages (from-to)i59-i61
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number2
DOIs
Publication statusPublished - 2007 Feb 1

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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