Peculiar physical properties of (ET)3(MnCl4)(TCE)

T. Naito; T. Inabe; K. Takeda; K. Awaga; T. Akutagawa; T. Hasegawa; T. Nakamura; T. Kakiuchi; H. Sawa; T. Yamamoto; H. Tajima

doi:10.1016/S0379-6779(00)00826-2

Peculiar physical properties of (ET)₃(MnCl₄)(TCE)

T. Naito, T. Inabe, K. Takeda, K. Awaga, T. Akutagawa, T. Hasegawa, T. Nakamura, T. Kakiuchi, H. Sawa, T. Yamamoto, H. Tajima

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The title compound (ET = bis(ethylene)dithiotetrathiafulvalene, TCE = 1,1,2-trichioroethane) is a new molecular conductor obtained by the standard electrochemical oxidation. It has a β″-donor arrangement without any crystallographic disorder or non-integral stoichiometry. The electrical behavior, which was sensitive to pressure, was semiconducting (35 Scm^-1 at RT) at ambient pressure with a clear hump around 60 K accompanied by a large hysterisis. No corresponding anomalies, however, were observed in its temperature-dependent magnetic susceptibility. The calculated band structure is two-dimensional, which agrees well with the observed physical properties.

Original language	English
Pages (from-to)	877-878
Number of pages	2
Journal	Synthetic Metals
Volume	120
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(00)00826-2
Publication status	Published - 2001 Mar 15
Externally published	Yes

Keywords

Organic conductors based on radical cation and/or anion salts

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/S0379-6779(00)00826-2

Cite this

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title = "Peculiar physical properties of (ET)3(MnCl4)(TCE)",

abstract = "The title compound (ET = bis(ethylene)dithiotetrathiafulvalene, TCE = 1,1,2-trichioroethane) is a new molecular conductor obtained by the standard electrochemical oxidation. It has a β″-donor arrangement without any crystallographic disorder or non-integral stoichiometry. The electrical behavior, which was sensitive to pressure, was semiconducting (35 Scm-1 at RT) at ambient pressure with a clear hump around 60 K accompanied by a large hysterisis. No corresponding anomalies, however, were observed in its temperature-dependent magnetic susceptibility. The calculated band structure is two-dimensional, which agrees well with the observed physical properties.",

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author = "T. Naito and T. Inabe and K. Takeda and K. Awaga and T. Akutagawa and T. Hasegawa and T. Nakamura and T. Kakiuchi and H. Sawa and T. Yamamoto and H. Tajima",

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TY - JOUR

T1 - Peculiar physical properties of (ET)3(MnCl4)(TCE)

AU - Naito, T.

AU - Inabe, T.

AU - Takeda, K.

AU - Awaga, K.

AU - Akutagawa, T.

AU - Hasegawa, T.

AU - Nakamura, T.

AU - Kakiuchi, T.

AU - Sawa, H.

AU - Yamamoto, T.

AU - Tajima, H.

PY - 2001/3/15

Y1 - 2001/3/15

N2 - The title compound (ET = bis(ethylene)dithiotetrathiafulvalene, TCE = 1,1,2-trichioroethane) is a new molecular conductor obtained by the standard electrochemical oxidation. It has a β″-donor arrangement without any crystallographic disorder or non-integral stoichiometry. The electrical behavior, which was sensitive to pressure, was semiconducting (35 Scm-1 at RT) at ambient pressure with a clear hump around 60 K accompanied by a large hysterisis. No corresponding anomalies, however, were observed in its temperature-dependent magnetic susceptibility. The calculated band structure is two-dimensional, which agrees well with the observed physical properties.

AB - The title compound (ET = bis(ethylene)dithiotetrathiafulvalene, TCE = 1,1,2-trichioroethane) is a new molecular conductor obtained by the standard electrochemical oxidation. It has a β″-donor arrangement without any crystallographic disorder or non-integral stoichiometry. The electrical behavior, which was sensitive to pressure, was semiconducting (35 Scm-1 at RT) at ambient pressure with a clear hump around 60 K accompanied by a large hysterisis. No corresponding anomalies, however, were observed in its temperature-dependent magnetic susceptibility. The calculated band structure is two-dimensional, which agrees well with the observed physical properties.

KW - Organic conductors based on radical cation and/or anion salts

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