Peculiar physical properties of (ET)3(MnCl4)(TCE)

T. Naito, T. Inabe, K. Takeda, K. Awaga, T. Akutagawa, T. Hasegawa, T. Nakamura, T. Kakiuchi, H. Sawa, T. Yamamoto, H. Tajima

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

The title compound (ET = bis(ethylene)dithiotetrathiafulvalene, TCE = 1,1,2-trichioroethane) is a new molecular conductor obtained by the standard electrochemical oxidation. It has a β″-donor arrangement without any crystallographic disorder or non-integral stoichiometry. The electrical behavior, which was sensitive to pressure, was semiconducting (35 Scm-1 at RT) at ambient pressure with a clear hump around 60 K accompanied by a large hysterisis. No corresponding anomalies, however, were observed in its temperature-dependent magnetic susceptibility. The calculated band structure is two-dimensional, which agrees well with the observed physical properties.

Original languageEnglish
Pages (from-to)877-878
Number of pages2
JournalSynthetic Metals
Volume120
Issue number1-3
DOIs
Publication statusPublished - 2001 Mar 15

Keywords

  • Organic conductors based on radical cation and/or anion salts

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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