Pd(III) mott-hubbard compounds

Shinya Takaishi, Masahiro Yamashita

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

In spite of long history of MX-chain complexes, all Pt or Pd compounds are in CDW state, without exception. We have recently succeeded in realizing Pd(III) MH state by two methods, that is, one is the chemical pressure via long alkyl chains introduced as counteranions, [Pd(en)2Br](C n-Y)2·4H2O, and the other is the partial substitution with Ni(III) ions, [Ni1-x Pd x (chxn)2Br]Br2. In both systems, it has been revealed that Pd(III) MH state was realized by the chemical pressure acting in the systems.

Original languageEnglish
Title of host publicationMaterial Designs and New Physical Properties in MX- and MMX-Chain Compounds
PublisherSpringer-Verlag Wien
Pages39-54
Number of pages16
Volume9783709113172
ISBN (Electronic)9783709113172
ISBN (Print)3709113164, 9783709113165
DOIs
Publication statusPublished - 2013 Jun 1

ASJC Scopus subject areas

  • Chemistry(all)

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  • Cite this

    Takaishi, S., & Yamashita, M. (2013). Pd(III) mott-hubbard compounds. In Material Designs and New Physical Properties in MX- and MMX-Chain Compounds (Vol. 9783709113172, pp. 39-54). Springer-Verlag Wien. https://doi.org/10.1007/978-3-7091-1317-2_4