Pd-catalyzed β-selective direct C-H bond arylation of thiophenes with aryltrimethylsilanes

Kenji Funaki, Tetsuo Sato, Shuichi Oi

Research output: Contribution to journalArticlepeer-review

75 Citations (Scopus)

Abstract

Direct arylation of thiophenes and benzothiophenes with aryltrimethylsilanes was effectively catalyzed by PdCl2(MeCN) 2 in the presence of CuCl2 as an oxidant. The reaction preferentially occurred at the β-position of both thiophenes and benzothiophenes.

Original languageEnglish
Pages (from-to)6186-6189
Number of pages4
JournalOrganic letters
Volume14
Issue number24
DOIs
Publication statusPublished - 2012 Dec 21

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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