Partially-oxidized Ni(dmit)2 salt with copper ions

K. Sakai, T. Akutagawa, T. Hasegawa, T. Nakamura

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The d-π hybrid charge-transfer system, Cu0.39[Ni(dmit)2] was prepared, and the crystal and electronic band structures were investigated. In the crystal, a unique layered structure is constructed, which results from the stacks of dimerized Ni(dmit)2 being largely slipped along the long molecular axis. The copper ions are located at the interlayer spaces with large thermal factors. From the tight-binding band calculation, a quasi-one-dimensional Fermi surface was obtained.

Original languageEnglish
Pages (from-to)805-806
Number of pages2
JournalSynthetic Metals
Volume120
Issue number1-3
DOIs
Publication statusPublished - 2001 Mar 15
Externally publishedYes

Keywords

  • Diffraction and scattering
  • Organic conductors based on radical cation and/or anion salts
  • X-ray emission

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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