Partial racemization occurring in the hydroxylactonization of a δ,ε-Epoxy Amide

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3 Citations (Scopus)

Abstract

Acid-promoted hydroxylactonization of a δ,ε-epoxy amide took place via both 6-exo-tet and 7-endo-tet processes, causing a considerable degree of racemization of the resulting δ-hydroxyalkyl-δ-lactone.

Original languageEnglish
Pages (from-to)2535-2537
Number of pages3
JournalBioscience, Biotechnology and Biochemistry
Volume74
Issue number12
DOIs
Publication statusPublished - 2010

Keywords

  • Baldwin rule
  • Dihydroisocoumarin
  • Epoxy amide
  • Hydroxylactonization
  • Racemization

ASJC Scopus subject areas

  • Biotechnology
  • Analytical Chemistry
  • Biochemistry
  • Applied Microbiology and Biotechnology
  • Molecular Biology
  • Organic Chemistry

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