Partial racemization occurring in the hydroxylactonization of a δ,ε-Epoxy Amide

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    2 Citations (Scopus)

    Abstract

    Acid-promoted hydroxylactonization of a δ,ε-epoxy amide took place via both 6-exo-tet and 7-endo-tet processes, causing a considerable degree of racemization of the resulting δ-hydroxyalkyl-δ-lactone.

    Original languageEnglish
    Pages (from-to)2535-2537
    Number of pages3
    JournalBioscience, Biotechnology and Biochemistry
    Volume74
    Issue number12
    DOIs
    Publication statusPublished - 2010

    Keywords

    • Baldwin rule
    • Dihydroisocoumarin
    • Epoxy amide
    • Hydroxylactonization
    • Racemization

    ASJC Scopus subject areas

    • Biotechnology
    • Analytical Chemistry
    • Biochemistry
    • Applied Microbiology and Biotechnology
    • Molecular Biology
    • Organic Chemistry

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