Parent Type Chemical Species Formed by Recoil Implantation Reaction in Tris(β-diketonato)metal(III)

T. Sekine, K. Yoshihara

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Chemical reactions induced by recoil implantation were studied focussing on parent type species in tris(β-diketonato)metal(III) complexes. The yield of the substitution reaction *M + M(acac)3 →*M(acac)3 + M was dependent on the force constant ratio K(*M —0)/K(M — O), showing that competition occurred between *M and M in the cage of the acetylacetonate complex. In the case of *Cr implantation in Co(acac)3, an exceptionally large yield could be explained by formation of Co(acac)2, whose central metal easily exchanges with *Cr, and by pickup of acac. When different β-diketonate complexes were examined in the reaction *Cr + M(β —dik)3 →*Cr(β-dik)3 + M the yield was dependent on the stability of the M(β — dik)3 complexes. A reaction model to explain these results reasonably was presented.

Original languageEnglish
Pages (from-to)65-70
Number of pages6
JournalRadiochimica Acta
Volume55
Issue number2
DOIs
Publication statusPublished - 1991 Aug

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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