Paramagnetic-diamagnetic phase transition accompanied by coordination bond formation-dissociation in the dithiolate complex Na[Ni(pdt)2] •2H2O

Shinya Takaishi, Nozomi Ishihara, Kazuya Kubo, Keiichi Katoh, Brian K. Breedlove, Hitoshi Miyasaka, Masahiro Yamashita

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Bis(2,3-pyrazinedithiolate)nickel complex Na[Ni(pdt)2] •2H2O formed one-dimensional stacks of the Ni(pdt)2 units and showed strong antiferromagnetic interactions along the stacking direction. A first-order phase transition between the paramagnetic and diamagnetic states, which was driven by dimerization of the Ni(pdt)2 units, accompanied by coordination bond formation, was observed.

Original languageEnglish
Pages (from-to)6405-6407
Number of pages3
JournalInorganic chemistry
Volume50
Issue number14
DOIs
Publication statusPublished - 2011 Jul 18

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Paramagnetic-diamagnetic phase transition accompanied by coordination bond formation-dissociation in the dithiolate complex Na[Ni(pdt)<sub>2</sub>] •2H<sub>2</sub>O'. Together they form a unique fingerprint.

  • Cite this