Palladium(0)-catalyzed domino cyclization-carbonylation of alkenyl- allenyl-allylic acetate

Takayuki Doi, Masaru Takasaki

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The Pd(0)-catalyzed domino cyclization-carbonylation of 5,8-dimethyl-5- (1,2-propadienyl)-2,8-nonadienyl acetate (7) was achieved at a rather higher temperature. The tricyclic and tetracyclic products, 15 and 16, were produced in 77% combined yield via five and six consecutive carbon-carbon bond formations, each step proceeding in > 94% yield.

Original languageEnglish
Pages (from-to)2929-2935
Number of pages7
JournalBulletin of the Chemical Society of Japan
Volume71
Issue number12
DOIs
Publication statusPublished - 1998 Dec 1
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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