Abstract
The silanedithiolato complex Pd(S2SiMe2)(PEt3)2 1 reacted with (C5H5)TiCl3 and TiCl4(thf)2 to produce the heterometallic clusters (C5H5)TiCl(μ-S)2Pd(PEt3)2 2 and TiCl2(S)(μ-S)2Pd2(PEt3)4 3 along with silicon-sulfur bond cleavage, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 988-989 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Volume | 2 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 2002 Jan 1 |
| Externally published | Yes |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Cite this
Komuro, T., Matsuo, T., Kawaguchi, H., & Tatsumi, K. (2002). Palladium dimethylsilanedithiolato complex: A precursor for Ti-Pd and Ti-Pd2 heterometallic complexes. Chemical Communications, 2(9), 988-989. https://doi.org/10.1039/b201702d