Palladium dimethylsilanedithiolato complex: A precursor for Ti-Pd and Ti-Pd2 heterometallic complexes

Takashi Komuro, Tsukasa Matsuo, Hiroyuki Kawaguchi, Kazuyuki Tatsumi

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The silanedithiolato complex Pd(S2SiMe2)(PEt3)2 1 reacted with (C5H5)TiCl3 and TiCl4(thf)2 to produce the heterometallic clusters (C5H5)TiCl(μ-S)2Pd(PEt3)2 2 and TiCl2(S)(μ-S)2Pd2(PEt3)4 3 along with silicon-sulfur bond cleavage, respectively.

Original languageEnglish
Pages (from-to)988-989
Number of pages2
JournalChemical Communications
Volume2
Issue number9
DOIs
Publication statusPublished - 2002 Jan 1
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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