Palladium dimethylsilanedithiolato complex: A precursor for Ti-Pd and Ti-Pd2 heterometallic complexes

Takashi Komuro; Tsukasa Matsuo; Hiroyuki Kawaguchi; Kazuyuki Tatsumi

doi:10.1039/b201702d

Palladium dimethylsilanedithiolato complex: A precursor for Ti-Pd and Ti-Pd₂ heterometallic complexes

Takashi Komuro, Tsukasa Matsuo, Hiroyuki Kawaguchi, Kazuyuki Tatsumi

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

The silanedithiolato complex Pd(S₂SiMe₂)(PEt₃)₂ 1 reacted with (C₅H₅)TiCl₃ and TiCl₄(thf)₂ to produce the heterometallic clusters (C₅H₅)TiCl(μ-S)₂Pd(PEt₃)₂ 2 and TiCl₂(S)(μ-S)₂Pd₂(PEt₃)₄ 3 along with silicon-sulfur bond cleavage, respectively.

Original language	English
Pages (from-to)	988-989
Number of pages	2
Journal	Chemical Communications
Volume	2
Issue number	9
DOIs	https://doi.org/10.1039/b201702d
Publication status	Published - 2002 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Palladium dimethylsilanedithiolato complex: A precursor for Ti-Pd and Ti-Pd2 heterometallic complexes",

abstract = "The silanedithiolato complex Pd(S2SiMe2)(PEt3)2 1 reacted with (C5H5)TiCl3 and TiCl4(thf)2 to produce the heterometallic clusters (C5H5)TiCl(μ-S)2Pd(PEt3)2 2 and TiCl2(S)(μ-S)2Pd2(PEt3)4 3 along with silicon-sulfur bond cleavage, respectively.",

author = "Takashi Komuro and Tsukasa Matsuo and Hiroyuki Kawaguchi and Kazuyuki Tatsumi",

year = "2002",

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doi = "10.1039/b201702d",

language = "English",

volume = "2",

pages = "988--989",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Palladium dimethylsilanedithiolato complex

T2 - A precursor for Ti-Pd and Ti-Pd2 heterometallic complexes

AU - Komuro, Takashi

AU - Matsuo, Tsukasa

AU - Kawaguchi, Hiroyuki

AU - Tatsumi, Kazuyuki

PY - 2002/1/1

Y1 - 2002/1/1

N2 - The silanedithiolato complex Pd(S2SiMe2)(PEt3)2 1 reacted with (C5H5)TiCl3 and TiCl4(thf)2 to produce the heterometallic clusters (C5H5)TiCl(μ-S)2Pd(PEt3)2 2 and TiCl2(S)(μ-S)2Pd2(PEt3)4 3 along with silicon-sulfur bond cleavage, respectively.

AB - The silanedithiolato complex Pd(S2SiMe2)(PEt3)2 1 reacted with (C5H5)TiCl3 and TiCl4(thf)2 to produce the heterometallic clusters (C5H5)TiCl(μ-S)2Pd(PEt3)2 2 and TiCl2(S)(μ-S)2Pd2(PEt3)4 3 along with silicon-sulfur bond cleavage, respectively.

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

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