Palladium-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates, ethylidene malononitriles, and allyltributylstannane

Shirong Lu; Tienan Jin; Ming Bao; Yoshinori Yamamoto

doi:10.1021/ol9029275

Palladium-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates, ethylidene malononitriles, and allyltributylstannane

Shirong Lu, Tienan Jin, Ming Bao, Yoshinori Yamamoto

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A novel Pd(0)-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates 1, ethylidene malononitriles 2, and allyltributylstannane 3 afforded a variety of multiosubstituted cyclopentenes 4 in good to high yields under mild reaction conditions.

Original language	English
Pages (from-to)	864-866
Number of pages	3
Journal	Organic letters
Volume	12
Issue number	4
DOIs	https://doi.org/10.1021/ol9029275
Publication status	Published - 2010 Feb 19

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol9029275

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title = "Palladium-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates, ethylidene malononitriles, and allyltributylstannane",

abstract = "A novel Pd(0)-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates 1, ethylidene malononitriles 2, and allyltributylstannane 3 afforded a variety of multiosubstituted cyclopentenes 4 in good to high yields under mild reaction conditions.",

author = "Shirong Lu and Tienan Jin and Ming Bao and Yoshinori Yamamoto",

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AU - Lu, Shirong

AU - Jin, Tienan

AU - Bao, Ming

AU - Yamamoto, Yoshinori

PY - 2010/2/19

Y1 - 2010/2/19

N2 - A novel Pd(0)-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates 1, ethylidene malononitriles 2, and allyltributylstannane 3 afforded a variety of multiosubstituted cyclopentenes 4 in good to high yields under mild reaction conditions.

AB - A novel Pd(0)-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates 1, ethylidene malononitriles 2, and allyltributylstannane 3 afforded a variety of multiosubstituted cyclopentenes 4 in good to high yields under mild reaction conditions.

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Palladium-catalyzed three-component [3 + 2] cycloaddition of propargyl trifluoroacetates, ethylidene malononitriles, and allyltributylstannane

Abstract

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